Z731412
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Z731412
Sigma
Stereoselective Polymerization with Single Site Catalysts
| ISBN-13: | 978-157444579-4 |
Description
| General description | This unified volume explains the mechanistic basics of tactic polymerizations, beginning with an extensive survey of the most important classes of metallocene and post-metallocene catalysts used to make polypropylenes. It also focuses on tactic stereoblock and ethylene/propylene copolymers and catalyst active site models, followed by chapters discussing the structure of more stereochemically complex polymers and polymerizations that proceed via non-vinyl-addition mechanisms. Individual chapters thoroughly describe tactic polymerizations of alpha olefins, styrene, dienes, acetylenes, lactides, epoxides, acrylates, and cyclic monomers, as well as cyclopolymerizations and ditactic structures, olefin/CO polymers, and metathesis polyalkenamers. |
Properties
| publication info | L. Baugh and J. Canich, CRC Press, 2008, 696 pp., hard cover |
Table Of Contents
| Table of Contents | POLYPROPYLENE: CATALYSTS AND MECHANISM Isotactic Polypropylene from C2- and Pseudo-C2-Symmetric Catalysts Fluorenyl-Containing Catalysts for Stereoselective Propylene Polymerization Substituted Indenyl and Cyclopentadienyl Catalysts for Stereoselective Propylene Polymerization Doubly Bridged Metallocenes for Stereoselective Propylene Polymerization Metallocenes with Donor/Acceptor and Other Heteroatom Bridges for Stereoselective Propylene Polymerization Stereoselective Propylene Polymerization with Early and Late Transition Metal Catalysts Catalyst Structure and Polymer Tacticity: The Theory Behind Site Control in Propylene Polymerization POLYPROPYLENE: APPLICATIONS OF TACTICITY Stereoblock Polypropylene Elastomeric Homo-Polypropylene: Solid State Properties and Synthesis via Control of Reaction Parameters Control of Molecular Weight and Chain-End Group in Tactic Polypropylenes Using Chain Transfer Agents Functionalization of Tactic Polypropylenes Influence of Tacticity of Propylene Placement on Structure and Properties of Ethylene/Propylene Copolymers OTHER MONOOLEFIN MONOMERS Stereocontrol in the Polymerization of Higher a-Olefin Monomers Tactic Polystyrene and Styrene Copolymers Cyclopentene Homo- and Copolymers Made with Early and Late Transition Metal Catalysts Tactic Norbornene Homo- and Copolymers Made with Early and Late Transition Metal Catalysts DIENE MONOMERS AND OLEFIN-CONTAINING POLYMERS The Stereoselective Polymerization of Linear Conjugated Dienes The Stereoselective Polymerization of Cyclic Conjugated Dienes Tactic Nonconjugated Diene Cyclopolymerization and Cyclocopolymerization Stereochemistry of Polymers Formed by Metathesis Polymerization of Bicyclic and Polycyclic Olefins Stereoregularity of Polyacetylene and Its Derivatives FUNCTIONAL AND NON-OLEFINIC MONOMERS Tacticity in Ethylene/Carbon Monoxide/Vinyl Co- and Terpolymerizations Stereoselective Acrylate Polymerization Discrete Catalysts for Stereoselective Epoxide Polymerization Stereoselective Polymerization of Lactide Glossary Index |
